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Rhenium(V) complexation with 4-methyl-1,2,4-triazolethiol-5 in 7 M hydrobromic acid

✍ Scribed by Amindzhanov, A. A.; Safarmamadov, S. M.; Maliki, Farishte; Mabatkadamova, K. S.


Book ID
121543902
Publisher
SP MAIK Nauka/Interperiodica
Year
2014
Tongue
English
Weight
315 KB
Volume
59
Category
Article
ISSN
0036-0236

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## Abstract The reaction of the heterocyclic enamine **1** with tosyl azide (**2**) leads to the tosylimino derivative **4** of 1,2,4‐triazolo[1,5‐a]pyrimidine. The extrusion of nitrogen from the primary adduct **3** is followed by a 1,2‐shift of a methyl group. The structure determination of **4**