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Rhenium complexes containing 1,1′-ferrocene dithiolato and diselenolato chelate ligands

✍ Scribed by Max Herberhold; Guo-Xin Jin; Wolfgang Milius


Book ID
103228476
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
454 KB
Volume
512
Category
Article
ISSN
0022-328X

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Polyhydride complexes of rhenium with th
✍ Sandra Bolaño; Jorge Bravo*; Soledad Garcı́a-Fontán* 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 145 KB

The reaction of [ReOCl 3 (AsPh 3 ) 2 ] with Ph 2 POCH 2 CH 2 OPPh 2 (L) in refluxing THF yielded the complex [ReOCl 3 L] (1). The new polyhydride [ReH 7 L] (2) was obtained by treating 1 with NaBH 4 in absolute ethanol. The heptahydride 2 is stable in the solid state but in solution dimerises, givin