✦ LIBER ✦

Rhenium catalyzed sulfurization of phosphorus(III) compounds with thiiranes: New reagents for phosphorothioate ester synthesis

✍ Scribed by Jeffrey B. Arterburn; Marc C. Perry

Book ID: 104258142
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 214 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)10029-6

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✦ Synopsis

A new method for the mild sulfurization of phosphorus(Ill) compounds with thiiranes catalyzed by ReOCI3(PPh3)2 (I) or ReOC13(SMe2)OPPh3) (II) is reported. The novel catalytic sulfur transfer reactions are rapid and occur efficiently under ambient conditions in organic solvents. This methodology enabled propylene sulfide to be used as a sulfurizing agent for the synthesis of a protected nucleotide phosphorothioate ester.

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ChemInform Abstract: Rhenium Catalyzed S

ChemInform Abstract: Rhenium Catalyzed Sulfurization of Phosphorus(III) Compounds with Thiiranes: New Reagents for Phosphorothioate Ester Synthesis.

✍ J. B. ARTERBURN; M. C. PERRY 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 1 views

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