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Revisiting p-coumarate esters production by Heck reaction

✍ Scribed by Gizelda O. Duque Estrada; Andréa Luzia F. de Souza; Joaquim F. Mendes da Silva; O.A.C. Antunes


Book ID
119216326
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
121 KB
Volume
9
Category
Article
ISSN
1566-7367

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The first examples of the synthesis of 1,3-dienyl sulfoxides by Heck reactions are described. Both racemic and enantiomerically pure exocyclic 1-p-tolylsulfinyl-1,3-dienes 1 are readily prepared by the intramolecular Heck reaction of their corresponding vinyl iodides in the presence of Pd(OAc) 2 as