✦ LIBER ✦
Reversibly-formed ion pairs are not involved during the solvolysis of N,O-diacetyl-N-arylhydroxylamines
✍ Scribed by Catherine M. Scott; Graham R. Underwood; Robert B. Kirsch
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 267 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Appropriate oxygen-18 labeling experiments demonstrate that N,O-diarylhydroxylamines do not undergo solvolysis via the reversible formation of ion pairs. This is in total conflict with the conclusions from previous indirect kinetic studies of these ultimate carcinogen models.