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Reversible Stereocontrol in the Lewis Acid Promoted Reaction of Alkoxyaldehydes Toward Various Allyltins.

✍ Scribed by Yutaka Nishigaichi; Akio Takuwa


Publisher
John Wiley and Sons
Year
2003
Weight
275 KB
Volume
34
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereochemical Chan
✍ H. UNO; N. MIZOBE; Y. YAMAOKA; N. ONO πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 37 KB πŸ‘ 2 views

Stereochemical Change in the Lewis Acid-Promoted Reaction of 2-Siloxypyrrole Derived from (L)-Glutamic Acid. Synthesis of a Lactacystin Analogue. -The enantiopure pyrrolooxazole (I) react with aliphatic aldehydes [cf. (II)] stereoselectively to yield either the isomers (IV) or (VIII) as major produ