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Reversible Photoswitchable Axially Chiral Dopants with High Helical Twisting Power

✍ Scribed by Green, Lisa; Venkataraman, Nithya; Shiyanovskaya, Irina; Khan, Asad; Urbas, Augustine; Doane, J. William; Li, Quan


Book ID
111898022
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
110 KB
Volume
129
Category
Article
ISSN
0002-7863

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## Abstract Axially chiral, __N__‐arylated 3,5‐dihydro‐4__H__‐dinaphtho[2,1‐__c__:1′,2′‐__e__]azepines have been prepared by short synthetic protocols from enantiopure 1,1′‐bi(2,2′‐naphthol) (BINOL) and anilines. Alkynes substituted with two __N__‐phenyldinaphthazepine donors readily undergo a form