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Reversible oxygenation of protoheme-imidazole complex in aqueous solution (1,2)

✍ Scribed by C.K. Chang; T.G. Traylor


Book ID
118310098
Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
339 KB
Volume
62
Category
Article
ISSN
0006-291X

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15N NMR shifts for imidazole and 1-methy
✍ Mohammed Alei Jr.; William E Wageman πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 French βš– 187 KB

The l5 N NMR frequencies for imidazole nitrogens undergo significant shifts when imidazole or l-methyl imidazole is taken from aqueous to CH2Cl2 solution. This shift is probably primarily due to strong hydrogen-bonding between 15N3 of imidazole and H20 protons in aqueous solution. It has been known