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Reversible Oxygenation of a Diphenylmethyl Radical Rendered Supramolecularly Persistent

โœ Scribed by Hirano, Takashi; Li, Wei; Abrams, Lloyd; Krusic, Paul J.; Ottaviani, M. Francesca; Turro, Nicholas J.


Book ID
127376165
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
42 KB
Volume
121
Category
Article
ISSN
0002-7863

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pToluenethiol/oxygen co-oxidation of 5-methylhepta-1,3,6-triene (2) gives inter alia only one (@) of four possible diastereoisomeric dioxolanes, and the threo-and erythro-isomers of the 1,4-addition product (l,O, 1,). The variation in relative yield= thiol concentration indicates that coupling of th