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Reversible opening and closing of hetero trimetallic units in (C5H5)2Y(THF)Re2H7(PMe2Ph)4 and (C5H5)2LuRe2H7(PMe2Ph)4

✍ Scribed by Alvarez, Daniel; Caulton, Kenneth G.; Evans, William J.; Ziller, Joseph W.


Book ID
119943624
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
456 KB
Volume
112
Category
Article
ISSN
0002-7863

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Syntheses and crystal structures of [(C6
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## CeH5CHzCsH4)2GdCl.THF]2 (1) and ( C ~H ~C H Z C ~H ~) ~E ~C I . T H F (2) were prepared by the reaction of LnC13 ( Ln=Gd, Er) with benzylcyclopentadienyl sodium in THF and characterized by elemental analysis, IR, 'H NMR, 13C NMR, MS and thermal gravimetry. The crystal structures of both compoun