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Reversible N−N Coupling of NO Ligands on Dinuclear Ruthenium Complexes and Subsequent N 2 O Evolution: Relevance to Nitric Oxide Reductase

✍ Scribed by Arikawa, Yasuhiro; Asayama, Taiki; Moriguchi, Yusuke; Agari, Shoko; Onishi, Masayoshi

Book ID
126111900
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
121 KB
Volume
129
Category
Article
ISSN
0002-7863

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Reactions of dinuclear metal carbonyl .a
Reactions of dinuclear metal carbonyl .alpha.-diimine complexes with alkynes. Part 2. Selective coupling of an .alpha.-diimine ligand and CO and methyl propynoate molecules to give Fe2(CO)n{(R)N:C(H)C(H)N(R)C(O)C(H):CC(O)OMe}, containing a flyover-type ligand and showing a reversible CO-induced metal-metal bond fission with x-ray crystal structures (n = 5, R = i-Pr; n = 6, R = c-hex)
✍ Muller, Fred.; Van Koten, Gerard.; Vrieze, Kees.; Heijdenrijk, Dick. 📂 Article 📅 1989 🏛 American Chemical Society 🌐 English ⚖ 993 KB