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Reversible isomerization of chromogenic dimers and the nature of azulene chromaticity

โœ Scribed by Yu. A. Mikheev; L. N. Guseva; Yu. A. Ershov


Book ID
110185139
Publisher
International Academic Publishing Co (Nauka/Interperiodica)
Year
2010
Tongue
English
Weight
245 KB
Volume
84
Category
Article
ISSN
0036-0244

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Irradiation (Iu> 400 nm) of solid pleiadiene (1) yields a single, head-to-head [,4, + r4,]-photodimer (2) the structure of which was determined by X-ray analysis. The formation of 2 is entirely suppressed at 77 K, since properly oriented pairs of molecules arise only from thermal disorder in crysta