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Reversible Intramolecular Base Stabilization of a Low-Coordinate Silicon Atom in the Silanediyl Complex [(o-Me2NCH2C6H4)2SiCr(CO)5]

✍ Scribed by Dipl.-Chem. Reiner Probst; Dipl.-Chem. Christian Leis; Dipl.-Chem. Siegfried Gamper; Dr. Eberhardt Herdtweck; Dr. Christian Zybill; Prof. Dr. Norbert Auner


Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
521 KB
Volume
30
Category
Article
ISSN
0044-8249

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The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.