✦ LIBER ✦

Reversible intermolecular energy transfer between saturated amines and benzene in non-polar solution

✍ Scribed by Arthur M. Halpern; Krystyna Wryzykowska

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 566 KB
Volume: 77
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(81)85605-9

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✦ Synopsis

c\c1tat10n of ^ ml\turc of dlmcrh]lerhylamlne (DELIA) and benzene m whexane at 27-Z nm prlmanly producesewned amme, \hde at 7-61 nm ewltcd benzene predomlnantlk results The fluorescence spectra appreciably overlap With 222 nm ewltarlon, DCSIA fluorescence IS quenched by benzene at the ddtuslon-controlled mc, thts quenchmg rcs~&s wth nearI\ umt etticwnc\ I" scnsltlzcd bcnzsnc IIuorrscence With 7-61 nm ewrtatlon, some sewwed DC&IA fluorescence IS obscr\ed rhe rate constat ior this process IS ~2.6 x IO9 hl-' 5-l * These values are obtamed using narrow-band condltlons (Le. a Guy spectrophotometer).

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