Reversible Insertion of Unactivated Alkenes into Silicon(II)-Tin Bonds
β Scribed by Rodriguez, Ricardo; Contie, Yohan; Gau, David; Saffon-Merceron, Nathalie; Miqueu, Karinne; Sotiropoulos, Jean-Marc; Baceiredo, Antoine; Kato, Tsuyoshi
- Book ID
- 120522275
- Publisher
- John Wiley and Sons
- Year
- 2013
- Tongue
- English
- Weight
- 750 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0044-8249
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π SIMILAR VOLUMES
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A homochiral porphyrin ruthenium(U) complex catalyzes the cyclopropanation of styrene derivatives with ethyl diazoacetate with good yields and moderate enantiomeric excesses (46-52 %). The catalyst is also active for diazocarbonyl compound insertion into S-H bonds, but with low ee.