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Reversible hydration of pteridine. General acid-base catalysis, solvent deuterium isotope effects, and transition state characterization

โœ Scribed by Pocker, Y.; Bjorkquist, D.; Schaffer, W.; Henderson, C.


Book ID
126285530
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
755 KB
Volume
97
Category
Article
ISSN
0002-7863

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Hydrogen-deuterium isotope effects for t
โœ P.J. Smith; S.K. Tsui ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 204 KB

In a recent publication2 the mechanism of the reaction of i-arylethyltrimethylammonium ions with ethoxide ion in ethanol at 70ยฐ was shown to be E2. The transition state for this process involved extensive proton transfer to base as exhibited by the observed trend in hydrogendeuterium isotope effects