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Reversible Gelation in Isotropic Solutions of the Helical Polypeptide Poly(γ-benzyl- l -glutamate): Kinetics and Formation Mechanism of the Fibrillar Network †

✍ Scribed by Tadmor, Rafael; Khalfin, Rafail L.; Cohen, Yachin

Book ID: 121507042
Publisher: American Chemical Society
Year: 2002
Tongue: English
Weight: 224 KB
Volume: 18
Category: Article
ISSN: 0743-7463
DOI: 10.1021/la0256026

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## Abstract The Zimm–Bragg parameters __s__ and σ were determined for poly(γ‐benzyl L‐glutamate) (PBLG) in __m__‐cresol and in dimethylformamide (DMF) from ORD data as a function of molecular weight. It was found that, within the temperature range between 10 and 55°C and on the average, __s__ = 1.6