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Reversible formal alkene insertion into a chelated platinum-alkyl bond

โœ Scribed by Flood, Thomas C.; Bitler, Steven P.


Book ID
126261642
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
280 KB
Volume
106
Category
Article
ISSN
0002-7863

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Triplet m-nitrophenyl nitrene reacts with frozen polycrystalline toluene at the benzylic position to give appreciable yields of a formal CH insertion adduct. This reaction does not occur on photolysis of m-nitrophenyl azide in toluene solution. Photoaffinity labelling (PAL) is a widely used techniqu