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Reversible cyclohexadiene-hexatriene valence isomerizations. A new class of photochromic compounds.

✍ Scribed by K.R. Huffman; M. Loy; Wm.A. Henderson Jr.; Edwin F. Ullman


Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
196 KB
Volume
8
Category
Article
ISSN
0040-4039

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By determining the E2 (and in part E,) redox potentials of the quinoid compounds 1-9, the close chemical similarity of the groups C = X [X = 0, N-CN, C(CN)\*] has been quantitatively confirmed. Especially the dicyanodiimines 2 and 5 are very similar to TCNQ derivatives 3. Substituent effects on the