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Reversible complex formation and kinetic substituent effects in the silver(I) ion induced bond reorganization of homocubanes

✍ Scribed by Leo A. Paquette; John S. Ward


Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
212 KB
Volume
13
Category
Article
ISSN
0040-4039

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✦ Synopsis


Reooimd inUSAlSeptembe$192; roooind iaUK for publiwtion 28 00tobor19'f2) 1,8-Bishomocubanes, homocubanes, and cubanes are recognized to undergo rmarkably facile valence isaaerizatim to less strained dicyclopropane isomers when treated with catalytic quantities of soluble Ag+ salts.' The precise manner in which such rearrangemnts