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Reversible Cation/Anion Extraction from K2La2Ti3O10: Formation of New Layered Titanates, KLa2Ti3O9.5 and La2Ti3O9.

✍ Scribed by Z. Serpil Goenen; Daniel Paluchowski; Peter Zavalij; Bryan W. Eichhorn; J. Gopalakrishnan


Publisher
John Wiley and Sons
Year
2007
Weight
17 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Syntheses and Crystal Structures of the
✍ Olivier Tougait; James A. Ibers πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 392 KB

The new compounds La 4 Ti 2 O 4 Se 5 and La 6 Ti 3 O 5 Se 9 have been obtained from stoichiometric reactions of La, Ti, TiO 2 , and Se in fused-silica tubes at 1223 K. Potassium halide 6uxes were used to promote the crystallization. The compounds have been characterized by single-crystal X-ray di4ra