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Reversible Carbon−Carbon Bond Heterolysis of a Hydrocarbon Derived from tert -Butylfulleride Ion and Tricyclopropylcyclopropenylium Ion

✍ Scribed by Kitagawa, Toshikazu; Tanaka, Toru; Murakita, Hideyuki; Takeuchi, Ken'ichi


Book ID
127388580
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
41 KB
Volume
64
Category
Article
ISSN
0022-3263

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The a-distonic sulphur-containing ion 'CH,&CH,), has been generated by transfer of CH: ' from ionized oxirane to dimethyl thioether and distinguished from the molecular ion of ethyl methyl thioether by collision induced dissociation (CID) experiments. In particular, the a-distonic ion expels CH, to