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Reversible aqueous metathesis reactions for potential application in dynamic combinatorial chemistry

✍ Scribed by Luke Hunter; Glenn C. Condie; Margaret M. Harding

Book ID
104098123
Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
702 KB
Volume
51
Category
Article
ISSN
0040-4039

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✦ Synopsis

a b s t r a c t Solutions of heterocycles having an allyl sulfide unit and simple alkenes in 50% t-BuOH/H 2 O undergo reversible olefin metathesis reactions with the second generation Hoveyda-Grubbs catalyst. The choice of functional groups is limited by competitive chelation of some heterocycles with the catalyst, and other stereoelectronic effects.

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