Traveling polymerization fronts in unstirred solutions of methylmethacrylate, methacrylic acid, or acrylamide with some free radicals initiators (through thermal decomposition) have been observed experimentally. A local heating of the initial reactant mixture, under suitable conditions, leads to a r
✦ LIBER ✦
Reversibility of the Propagation Reaction in Polymerization Processes and its Manifestation in the Phenomenon of a ‘Ceiling Temperature’
✍ Scribed by DAINTON, F. S.; IVIN, K. J.
- Book ID
- 109558270
- Publisher
- Nature Publishing Group
- Year
- 1948
- Tongue
- English
- Weight
- 340 KB
- Volume
- 162
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/162705a0
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## Abstract This paper studied the polymerization‐induced phase separation phenomenon (spinodal decomposition) in a model binary polymer solution under a linear spatial temperature gradient for the purpose of fabricating anisotropic polymeric materials by using mathematical modeling and computer si