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Reversed-phase liquid chromatographic enantioseparation by cycloalkylcarboxylates of cellulose and amylose

✍ Scribed by Takateru Kubota; Chiyo Yamamoto; Yoshio Okamoto

Book ID
102075780
Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
119 KB
Volume
16
Category
Article
ISSN
0899-0042

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✦ Synopsis

Abstract

Three novel cycloalkylcarboxylates, cyclopentyl, cyclohexyl, and 1‐adamantylcarboxylates of cellulose and amylose were prepared and their chiral recognition abilities as chiral stationary phases (CSPs) for high‐performance liquid chromatography (HPLC) were evaluated using a methanol–water mobile phase. Among these esters, cellulose tris(cyclohexylcarboxylate) showed a relatively high chiral recognition ability. The 1‐adamantylcarboxylates of cellulose and amylose showed dissimilar chiral recognition abilities from the other two, probably due to the low degree of substitution and the high hydrophobicity of this group. Chirality 16:309–313, 2004. © 2004 Wiley‐Liss, Inc.

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