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Reversal of Diastereoselectivity of Mesitonitrile Oxide 1,3-Dipolar Cycloadditions with Penta-1,4-diene-3-ol by Mg(II).

โœ Scribed by P. Micuch; L. Fisera; M. K. Cyranski


Publisher
John Wiley and Sons
Year
2005
Weight
17 KB
Volume
36
Category
Article
ISSN
0931-7597

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Diastereo-and Enantioselective Synthesis of โˆ† 2 -1,2,4-Oxadiazolines by 1,3-Dipolar Cycloaddition of Nitrile Oxides with Chiral Hydrazones. -1,3-Dipolar cycloaddition of phenyl nitrile oxide with chiral hydrazones (I) affords โˆ† 2 -1,2,4-oxadiazolines (III) with low to excellent diastereoselectiviti