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Reversal of an enzymatic decarboxylation: Thiamin mediated carboxylation of acetaldehyde into pyruvic acid

✍ Scribed by Marie-Anne E. Foppen; Yvonne M. de Lange; Fred van Rantwijk; Leendert Maat; Antonius P. G. Kieboom

Book ID: 104589192
Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 110 KB
Volume: 109
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19901090508

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✦ Synopsis

Abstract

Acetaldehyde has been converted into pyruvic acid (42% yield) via the reaction of 2 ‐(1‐hydroxyethyl)thiamin (3) with carbon dioxide at 50 atm. (DMF, 20 C).

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