Reusable Cobalt(III)-Salen Complex Supported on Activated Carbon as an Efficient Heterogeneous Catalyst for Synthesis of 2-Arylbenzimidazole Derivatives
✍ Scribed by Hashem Sharghi; Mahdi Aberi; Mohammad Mahdi Doroodmand
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 441 KB
- Volume
- 350
- Category
- Article
- ISSN
- 1615-4150
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Various 2‐arylbenzimidazoles were synthesized from phenylenediamines and aromatic aldehydes via a one‐step process in the presence of a catalytic amount of a cobalt‐salen complex supported on activated carbon [CoxO‐Co(salen) 11] at room temperature. The salient features of this method include mild conditions, short reaction times, high yields, easy purification, recyclable catalyst, large‐scale synthesis and simple procedure. The reactions were performed in ethanol and the catalyst could be reused for several cycles without a decrease in activity. The heterogeneous catalyst was characterized by powder X‐ray diffraction (XRD), scanning electron microscopy (SEM), atomic forced microscopy (AFM), thermogravimetric (TG) methods for analysis of nitrogen adsorption and FT‐IR spectroscopy. Leaching experiments showed that the catalyst is most strongly anchored to the activated support after 10 cycles of reuse.