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Reusable and environmentally friendly ionic trinuclear iron complex catalyst for atom transfer radical polymerization

✍ Scribed by Niibayashi, Shota; Hayakawa, Hitoshi; Jin, Ren-Hua; Nagashima, Hideo

Book ID: 124051325
Publisher: Royal Society of Chemistry
Year: 2007
Tongue: English
Weight: 216 KB
Volume: 18
Category: Article
ISSN: 1359-7345
DOI: 10.1039/B617722K

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## Abstract The bimetallic ruthenium complex [(1,3,5‐__i__‐Pr~3~C~6~H~3~)Ru(μ‐Cl)~3~RuCl(C~2~H~4~)(PCy~3~)] has been synthesized by reaction of [(1,3,5‐__i__‐Pr~3~C~6~H~3~)RuCl~2~)]~2~ with one equivalent of PCy~3~ in the presence of ethylene. It can be used as a catalyst precursor for the controll