Retrograde Michael Reaction in Additions of Active Methylene Compounds to Tetracyanoethylene 1
β Scribed by Dyke, J. W. Van; Snyder, H. R.
- Book ID
- 127272438
- Publisher
- American Chemical Society
- Year
- 1962
- Tongue
- English
- Weight
- 333 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0022-3263
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## Abstract Palladium on carbon (10β% Pd/C) efficiently catalyzes the (retroβ)Michael addition of activated methylene compounds **2a**β**d**, such as malononitrile (**2b**), to monoβ and doubly activated styrenes **1a**β**h** to give the adducts **3a**β**l**. The scope and limitations are described