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Retro Diels–Alder and other electron ionization-induced fragmentation reactions of 1,2,3,4-tetrahydrobenzopyran-2,3-dicarboxylic acid derivatives

✍ Scribed by Rafał Szmigielski; Witold Danikiewicz; Karolina Dolatowska; Krzysztof Wojciechowski


Book ID
108146453
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
381 KB
Volume
248
Category
Article
ISSN
1387-3806

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The stereoisomeric 2,3-cis-and 2,3-trans-3-methoxytricyclo [ 6.2.2.02,7 ] dodeca-9-enes endo-1 and exo-1 (endo and exo refer to the methoxy group) exhibit di †erent behavior under electron ionization (EI) : the m/z 80 cyclohexa-1,3diene radical cation formed by retro-Diels-Alder (RDA) fragmentation