RETRACTED: A theoretical study of the ligand-exchange reactions of Na+·X complexes (X=O,O2,N2,CO2 and H2O): implications for the upper atmosphere
✍ Scribed by Sophia E. Daire; John M.C. Plane; Stuart D. Gamblin; Pavel Soldán; Edmond P.F. Lee; Timothy G. Wright
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- English
- Weight
- 207 KB
- Volume
- 64
- Category
- Article
- ISSN
- 1364-6826
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Upper limits of and were established for 4 ϫ 10 7 ϫ 10 cm molecule s the gas-phase reactions of H 2 O 2 with O 3 and NO, respectively. These reactions are too slow to explain features observed in the atmospheric vertical profile of H 2 O 2 .
Ab initio calculations suggest that the potential energy surface for the 1 2\_~" state of N,O' has ;! secondary nljnimunl corresponding to a stron+ bent structure. This structure is computed to lie below the x'XT smtc cner~elically and therefore may be responsible for the isotopic scrnnrblin~ observ
Emissions at 450 nm and 4.27 ~sm have been measured when a vaxiety of mixtures containing H 2, CO. either 02 or NaO, and Ar were heated behind reflected shock waves to temperatures of 2000-2850 K and total concentrations near 5 x 101| molecule/era 3. These emissions were used to obtain absolute con