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Retinal Analog Study of the Role of Steric Interactions in the Excited State Isomerization Dynamics of Rhodopsin †

✍ Scribed by Kochendoerfer, Gerd G.; Verdegem, Peter J. E.; van der Hoef, Ineke; Lugtenburg, Johan; Mathies, Richard A.

Book ID
126981329
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
823 KB
Volume
35
Category
Article
ISSN
0006-2960

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On the role of the triplet state in the
On the role of the triplet state in the cis/trans isomerization of rhodopsin: A CASPT2//CASSCF study of a model chromophore
✍ Remedios González-Luque; Gloria Olaso-González; Manuela Merchán; Pedro B. Coto; 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 244 KB

## Abstract The possibility of population of the lowest‐lying triplet state (__T__~1~) in the early events of the photochemical isomerization process of a model chromophore of Rhodopsin (Rh) has been analyzed using multireference perturbation theory (CASPT2//CASSCF) methods. It is shown that the ch