Retention prediction of large and condensed polycyclic aromatic hydrocarbons in reversed-phase microcolumn liquid chromatography with diphenylsilica stationary phase
β Scribed by Jinno, K. ;Katoh, T. ;Okamoto, M. ;Fetzer, J. C. ;Biggs, W. R.
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 528 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0935-6304
No coin nor oath required. For personal study only.
β¦ Synopsis
The retention behavior of condensed large polycyclic aromatic hydrocarbons has been investigated with diphenylsilica stationary phases in reversed-phase microcolumn liquid chromatography. The results were correlated with two parameters which indicate size and shape of the molecules. Since the resulting equation can be used for retention prediction of large polycyclic aromatic hydrocarbons, computer-assisted "standardless" identification is accomplished for "unknown" compounds contained in the standard.
π SIMILAR VOLUMES
Preparative-grade bonded pand y-cyclodextrin stationary phases were used as the packing material of liquid chromatographic analytical microcolumns. Although the resulting columns are characterized by relatively low efficiency, the high selectivity of the cyclodextrin phases nevertheless allows their
A novel chemically bonded phase was evaluated for its applicability in Ε½ . discriminating among polycyclic aromatic hydrocarbons PAHs in terms of molecular size, planarity, and shape selectivity. It was observed that planar molecules were more retained than nonplanar analogues and that the retention
## Abstract The retention behavior of aromatic hydrocarbons and dansylamino acids on cationβexchangers modified with alkylammonium ions has been examined by microcolumn liquid chromatography. Several parameters affected the retention of analytes, involving concentration of the modifier in the mobil
## Abstract A chemically bonded C~60~ silica phase was synthesized as a stationary phase for liquid chromatography (LC) and its retention behavior evaluated for various polycyclic aromatic hydrocarbons (PAHs) using microcolumn LC. The results indicate that the C~60~ bonded phase offers selectivity