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Retention of Configuration in the Opening of cis- and trans-Dypnone Oxides 1

✍ Scribed by Wassfrman, Harry H.; Aubrey, Norman E.


Book ID
124099410
Publisher
American Chemical Society
Year
1956
Tongue
English
Weight
364 KB
Volume
78
Category
Article
ISSN
0002-7863

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The configuration and conformation of some diastereomeric 4-hydroxy-cis-and -h.uns-l-oxadecalins were inferred by 'H and '3C NMR spectroscopy. The results obtained indicate that the cis-fused compounds are conformationally homogeneous, having the oxygen atom attached to the cyclohexyl ring in the ax