Retarded styrene anionic polymerization, 7. Influence of mono- and diphenoxymagnesium derivatives on both the reactivity and thermal stability of polystyryllithium species at high temperature

Towards the control of the reactivity in

Towards the control of the reactivity in high temperature bulk anionic polymerization of styrene, 1. Influence of n,s-dibutylmagnesium on the reactivity of polystyryllithium species

✍ Philippe Desbois; Michel Fontanille; Alain Deffieux; Volker Warzelhan; Stephan L 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 105 KB 👁 2 views

The influence of n,s-dibutylmagnesium on the kinetics of styrene polymerization initiated by sbutyllithium was investigated in cyclohexane at 50 8C. The presence of n,s-dibutylmagnesium, in molar ratios ranging from 0 to 20 with respect to polystyryllithium, leads to a drastic and continuous reducti