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Restriction of the C6N6 bond rotation of adenosine compounds investigated by1H- and15N-NMR spectra

✍ Scribed by Uzawa, Jun ;Anzai, Kentaro

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
164 KB
Volume
1988
Category
Article
ISSN
0947-3440

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✦ Synopsis

If khc C6-N6 bond of an adenosine compound has a partial double bond character as is the case of the 3,5'-cycloadenosine compound 2, the C6-N" bond rotation is restricted, as is observed by 'Hand "N-NMR spectra. ' ) K. Anzai, M. Matsui, Agric. Bid. Chem. Jpn. 37 (1973) 301; *) The signal for acyl-N= is not detected in the "N-INEPT NMR [I 45/88]

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