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Restricted Rotation in Arylamines. I. Preparation and Resolution of N-Succinyl-N-methylbromomesidine

✍ Scribed by Adams, Roger; Dankert, L. J.


Book ID
127101913
Publisher
American Chemical Society
Year
1940
Tongue
English
Weight
302 KB
Volume
62
Category
Article
ISSN
0002-7863

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Enantiomers as a result of restricted ro
✍ Helene VΓΆlter; GΓΌnter Helmchen πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 219 KB

We wish to report the first separations of enantiomeric N-nitrosamines, thioamides and amides, whose chirality is the result of asymmetry caused solely by restricted rotation about partial double bonds. Specifically, compounds l, 2 and 3 were obtained optically active.