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Restricted quantum exchange theory for intramolecular vibrational relaxation in polyatomic molecules

✍ Scribed by James Stone; Everett Thiele; Myron F. Goodman

Publisher: Elsevier Science
Year: 1980
Tongue: English
Weight: 536 KB
Volume: 71
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(80)85314-0

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✦ Synopsis

We pose and solve a new quantum statistical counting problem and develop it fiuther to obtam a theory for intramokmlar vIbratIona couphng. Simple analytlul expresnons are presented for T1 and Tz relautlon rates. The formulas predict. m agreement wth expenments. that tigh energy linewdths are nearly energy Independent.

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