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Restraining Symmetry in the Formation of Small Polyoxomolybdates: Building Blocks of Unprecedented Topology Resulting from “Shrink-Wrapping” [H2Mo16O52]10--Type Clusters.

✍ Scribed by De-Liang Long; Paul Koegerler; Louis J. Farrugia; Leroy Cronin

Book ID: 101950611
Publisher: John Wiley and Sons
Year: 2003
Weight: 88 KB
Volume: 34
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200347022

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Restraining Symmetry in the Formation of

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Trapped polyoxometalate clusters can be isolated in a novel and simple synthetic approach which "shrink-wraps" unstable, unsymmetrical polyoxometalate clusters with large organic cations. This prevents their rearrangement and aggregation to more symmetrical, well known structures. Initial results an