Transfer of one quantum of vibrational excitation from a CO molecule initizlly in vibrational Iwel 1G to another CO mofecul~ inSalty in its ground vibrational level, a process endothermic by about 236 cm -I, is explained by a second-order distortrd-tive Born calculation. The distortion potent&l is r
Resonance transfer of molecular excitation energy: Enhancement in channels
β Scribed by J. Mahanty; B.W. Ninham
- Book ID
- 103768018
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 154 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0375-9601
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π SIMILAR VOLUMES
Exact computations for rotational excitation are compared with the close-coupling approximation and with improved schemes which incorporate adiabatically the closed channels. The "direct ~ transition probability and the resonance energies can be predicted by a modified close-coupling scheme.
## Abstract A linear molecular polymer chain formed by replacing two host molecules by two identical impurities is investigated. Applying a particular theoretical approach the energies of localized excitations appearing in the system are determined and the dependence of these energies on the distan