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Resonance-stabilized carbanions. II. Rotational barriers in phenylallyl alkali metal salts

โœ Scribed by Sandel, Vernon R.; McKinley, Suzanne V.; Freedman, Harold H.

Book ID
124165422
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
298 KB
Volume
90
Category
Article
ISSN
0002-7863

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While fluorescence can be clearly observed in resonance-stabilized acyclic anions, its occurrence is insufficient for unambiguous assignment of either ion-pairing type or anion geometry. As. in cyclic, aromatic anions, the requirement for contact ion-pairing is less severe in the excited state than