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Resonance Raman studies of the mechanism of photoreduction of iron protoporphyrin-IX dimethyl ester in the presence of axial ligands

โœ Scribed by A. L. Verma; N. K. Chaudhury


Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
820 KB
Volume
22
Category
Article
ISSN
0377-0486

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Photoreduction of Fe(TPP)Cl in CH2Cl2 an
โœ P. K. Shantha; H. H. Thanga; A. L. Verma ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 228 KB ๐Ÿ‘ 3 views

Coordination of 1,2-dimethylimidazole to chloroiron(III)tetraphenylporphyrin [ Fe(TPP)Cl ] in (1,2-Me 2 Im) DMSO and neat without alcohol results in clean reduction at the iron centre on photoexcita-CH 2 Cl 2 , 1,2-Me 2 Im tion at 441.6 nm. Fe(TPP)Cl also photoreduces in in the presence of 2-methyli