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Resonance Raman spectroscopy of non-planar nickel porphyrins

✍ Scribed by J. A. Shelnutt; S. A. Majumder; L. D. Sparks; J. D. Hobbs; C. J. Medforth; M. O. Senge; K. M. Smith; M. Miura; L. Luo; J. M. E. Quirke

Book ID
102921122
Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
692 KB
Volume
23
Category
Article
ISSN
0377-0486

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Porphyrins exhibiting ideal symmetry show depolarization ratios of their Raman-active and D 4h A 1g , B 1g , B 2g A 2g type vibrations which are independent of the wavenumber of the exciting radiation, namely 0.125 for 0.75 for A 1g , and and inÐnite for modes. Symmetry-lowering distortions, which c