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Resonance Raman spectra of n-methylthioacetamide

✍ Scribed by Yoko Sugawara; Hiro-o Hamaguchi; Issei Harada; Takehiko Shimanouchi

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 398 KB
Volume: 52
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80551-4

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✦ Synopsis

Rigorous resonance, as well as prcrcsonancc Raman spectra of N-mcthyltllio,~cctalllide and its N-dcuterated compound arc reported. The obscrvcd sclcctivity in the resonance intensity enhancement ir; dwussed in rclatlon to the potcntl,ll energy dlstributlons obt;iined by normal coordinate trmtmcnt. The structural change conccrnlng the C -N .uld C-S bond length is suggested to accompany the x* + H electronic cucitation.

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