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Resonance raman spectra of meso-tetramethylporphine, meso-tetraethylporphine and their nickel complexes measured by using the sers technique

✍ Scribed by Yasushi Shiratori; Masanori Serita; Koichi Itoh


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
365 KB
Volume
118
Category
Article
ISSN
0009-2614

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✦ Synopsis


Surface-enhanced resonance Raman scattering spectroscopy was apphed 10 measure the vibrational spectra of mesctetramcthylporphine (IMP), meso-letraethylporphine VP). and their nickel complexes in layered structures having CaF+amplc/Ag (strucrurc I) and c_sF,/Ag/samplc (structure II) configurations. The surraoc spectra clearly prove thaL when the samples come into contact wilh Ag atoms (slructure I) or a vacuuti,deposited Ag film (struclure II), they undergo chemical processes such as meral-incorporation and melal-exchange reactions, and a structural change