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Resonance Raman spectra of horseradish peroxidase. Evidence for anomalous heme structure

✍ Scribed by Rakshit, Gopa; Spiro, Thomas G.


Book ID
127218560
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
705 KB
Volume
13
Category
Article
ISSN
0006-2960

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Resonance Raman and electronic absorptio
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The resonance Raman (RR) and electronic absorption spectra of ferric horseradish peroxidase isozyme A2 (HRPA2) and of its complex with Γ‘uoride are reported. The data show the presence of a Ðve-coordinate quantummixed spin (QS) species, resulting from the admixture of intermediate-spin, S = 3/2, and