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Resonance Raman scattering from hyperporphyrin absorption bands of molybdenum tetraphenylporphyrin

✍ Scribed by James Terner; Joseph Topich

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 383 KB
Volume: 106
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85372-5

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✦ Synopsis

Escitation within the "hype?-type absorption of osothiocyanato molybdenum(V) tetraphenylporphyrin results in behavior of the resonance Raman scattering that is different from that usually observed for porphyrins. Excitation within the charge-transfer absorption in the near UV gives suttcring of AIg and Alg modes, while escitation within the strongly red-shifted Soret band fives cnhwcemenr of Big and Bzg modes.

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