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Resonance Raman scattering and depolarization dispersion of a degenerate, Jahn-Teller active mode

✍ Scribed by M. Pawlikowski; M.Z. Zgierski


Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
466 KB
Volume
48
Category
Article
ISSN
0009-2614

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✦ Synopsis


Rccclvcd 4 I-cbrudry 1977 WC have annlyxd the rc\onancc Ramnn sattering (RRS) from a degenerate mode mvolved m an ITI X e type I.dm -Tclkr coup!uq. It 19 shown that the prcccncc of ,I quadratrc vibronrc mtcractton producer depohz~t~on dkperkm m the ov"rtoncc of this mode. Thcrcforc such a dqcrsion can serve as an mdxatron of the prcsencc of a quadratic couplm~, w that RRS from B dcgcneratc. L-type clcctromc st.ltc cm grvc more information on vibronic coupling than .m A.xorption spectrum.


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Resonance Raman spectra and excitation profiles associated with Renner-Teller coupIing in square molecules are ar&ysed theoretically and an experiment is proposed to warch for this effect in metalioporphyrins-One of the most successful applications of resonance Raman spectroscopy to date has been th