Resonance Raman scattering and depolarization dispersion of a degenerate, Jahn-Teller active mode
β Scribed by M. Pawlikowski; M.Z. Zgierski
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 466 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
Rccclvcd 4 I-cbrudry 1977 WC have annlyxd the rc\onancc Ramnn sattering (RRS) from a degenerate mode mvolved m an ITI X e type I.dm -Tclkr coup!uq. It 19 shown that the prcccncc of ,I quadratrc vibronrc mtcractton producer depohz~t~on dkperkm m the ov"rtoncc of this mode. Thcrcforc such a dqcrsion can serve as an mdxatron of the prcsencc of a quadratic couplm~, w that RRS from B dcgcneratc. L-type clcctromc st.ltc cm grvc more information on vibronic coupling than .m A.xorption spectrum.
π SIMILAR VOLUMES
Resonance Raman spectra and excitation profiles associated with Renner-Teller coupIing in square molecules are ar&ysed theoretically and an experiment is proposed to warch for this effect in metalioporphyrins-One of the most successful applications of resonance Raman spectroscopy to date has been th