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Resonance Raman and infrared spectroscopy of carbon nanotubes

✍ Scribed by J. Kastner; T. Pichler; H. Kuzmany; S. Curran; W. Blau; D.N. Weldon; M. Delamesiere; S. Draper; H. Zandbergen


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
604 KB
Volume
221
Category
Article
ISSN
0009-2614

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✦ Synopsis


We present a comparative analysis of the vibrational and structural properties of carbon nanotubes. The first-order Raman spectrum exhibits two lines at 1582 cm -' and at 1350 cm-'. The observed ratio of the integrated intensity of these lines was found to be different as compared to polycrystalline graphite. The position and intensity of the line around 1350 cm-' strongly depend on the energy of the exciting laser line. This dispersion effect is again different from the dispersion in nanocrystalline graphite. It is discussed in terms of a photoselective resonance process. Transmission infrared spectra of the nanotubes show one broad and asymmetric line at 1575 cm-' and a weaker line at 868 cm-'.


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